Product ID:DIESEL FUEL-2
MSDS Date:01/15/1992
FSC:9140
NIIN:00-247-4362
MSDS Number: CGLRL

VALERO REFINING CO

1200 SMITH ST SUTE 900
HOUSTON, TX 77052-3720
US

Emergency Phone: 713-951-2000

Info Phone: 713-951-2000

Cage: 5V642

VALERO REFINING

CORPUS CHRISTI, TX 78469 US

Telephone: 512-289-6000

Cage: 5V642

AROMATIC HYDROCARBON

CAS: 68333-88-0

Fraction By Weight: 10 - 30%

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

ALIPHATIC HYDROCARBON/NO. 2 DIESEL FUEL

CAS: 68334-30-5

RTECS: HZ1800000

Fraction By Weight: >60%

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

LD50 LC50 Mixture:TLV FOR OIL MIST IS 5 MG/M3.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- EYE:CAN CAUSE SEVERE IRRITATION.
SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION. INHALE:OIL
MIST MAY CAUSE IRRITATION OF UPPER RESPI RATORY TRACT, CNS EFFECTS.
ORAL:MAY RESULT IN VOMITING. ASPIRATION MUST BE AVOIDED. CHRONIC-
DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SEVERE IRRITATION, NAUSEA, VOMITING, TEARING,
BLURRED VISION, DERMATITIS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE
TO THE EFFECTS OF THIS PRODUCT.

First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO
NOT INDU CE VOMITING. SEEK MEDICAL ATTENTION. IFSPONTANEOUS
VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF
VOMITUS INTO LUNGS.

Flash Point:150F,66C
Extinguishing Media:USE CARBON DIOXIDE (CO2), FOAM OR DRY CHEMICAL. USE
WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. VAPORS ARE HEAVIER THAN AIR
AND CAN TRAVEL TO AN IGNITION SOURCE AND BURN. CONTAINER MAY BURST.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA.
CONTAIN AND PICK UP SPILL WITH NON-FLAMMABLE ABSORBENT SUCH AS
SAND, EARTH, VERMICULITE. PREVENT LIQUID FROM ENTERING SEWERS OR
WATERWAYS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN COOL PLACE AWAY FROM IGNITION
SOURCES AND STRONG OXIDIZING AGENTS.
Other Precautions:COMBUSTIBLE. "EMPTY" CONTAINERS MAY RETAIN RESIDUE
AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER
OR DRILL. KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING VAPORS. DO
NOT GET IN EYE, ON SKIN OR ON CLOTHING. AVOID INGESTION

Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV IS EXCEEDED OR
FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR
RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRES SURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:RUBBER FOR PROLONGED/REPEATED CONTACT
Eye Protection:SAFETY GLASSES OR GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND BEFORE EATING OR
DRINKING.
Supplemental Safety and Health

HCC:V4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:390F,199C
Vapor Pres:<2 @ 60F
Vapor Density:>1
Spec Gravity:0.85
Evaporation Rate & Reference:<1 (ETHER=1)
Appearance and Odor:LIQUID, HYDROCARBON ODOR
Percent Volatiles by Volume:10- 30

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAMES
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON
DIOXIDE, HEAVY SMOKE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. REUSING OR INCINERATION IS RECOMMENDED. THIS
IS AN OIL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.